Ray Group

@AKRay_HU

Berlin, Germany chemie.hu-berlin.de/de/forschung/r… Joined January 2023

126 Following 555 Followers 59 Posts

Latest posts 5

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Ray Group @AKRay_HU Jan 17, 2024

Starting the year with a bang @NatureChemistry ! Though It took us 4 PhD, 2 postdocs, and 8 years to solve the mystery. Congratulations Dustin and Virginia from @UMLehnertgroup. Read it here now. @UniSysCat @HumboldtChem
nature.com/articles/s4155…

www.nature.com Trapping of a phenoxyl radical at a non-haem high-spin iron(II) centre Nature Chemistry - The activation of dioxygen at metal centres, and subsequent functionalization of unactivated C‒H bonds, requires the generation of high-energy radical intermediates that...

Ray Group @AKRay_HU Oct 9, 2024

@UniSysCat research groups in collaboration with ak_Meyer and @MunzDominik now trap and spectroscopically characterize a diiron(IV)bis-oxo diamond core relevant to soluble methane monooxygenase by dioxygen activation @HumboldtChem
pubs.acs.org/doi/abs/10.102…

pubs.acs.org A bis-Phenolate Carbene-Supported bis-μ-Oxo Iron(IV/IV) Complex with a [FeIV(μ-O)2FeIV] Diamond... Abstract. The diiron(II) complex, [(OCO)Fe(MeCN)]2 (1, MeCN = acetonitrile), supported by the bis-phenolate carbene pincer ligand, 1,3-bis(3,5-di-tert-

Ray Group @AKRay_HU Sep 11, 2024

Thrilled to announce that our recent article is featured on the front cover of this month's @J_A_C_S. Check out the full article here. doi.org/10.1021/jacs.4…
@ACS4Authors @HumboldtUni @UniSysCat
#MyACSCover

Ray Group @AKRay_HU Aug 26, 2024

Big congrats to Laurice on successfully defending your Bachelor's thesis! Wishing you continued success in your future endeavours.

Ray Group @AKRay_HU Jul 5, 2024

Unisyscat groups now report an unusual S=1 Fe(III)-O2-Cu(II) complex that reproduces the blue color and 750 cm-1 rRaman band of the as-isolated CcO. A pure non-heme approach provides vital insights to CcO reactivity. @acsJACS
pubs.acs.org/doi/10.1021/ja…
@HumboldtChem @UniSysCat

pubs.acs.org A Bioinspired Nonheme FeIII–(O22–)–CuII Complex with an St = 1 Ground State Abstract. Cytochrome c oxidase (CcO) is a heme copper oxidase (HCO) that catalyzes the natural reduction of oxygen to water. A profound understanding of so