Gevorgyan Lab

Check out our review discussing the early development and recent advances in photoexcited transition metal-catalysed HAT processes. @NatureCatalysis

Congrats to Kallol, Ayala, our collaborators from Armenia-Hasmik & prof. Robert Hakobyan for great effort!
nature.com/articles/s4192…

Direct C–H alkylation could be a very useful strategy for rapidly building molecular diversity, including 3° & 4° carbon centers. Congrats Subham & Gaurav on developing Light-Induced Pd-Catalyzed Allylic C–H Alkylation of Internal Alkenes! out in @J_A_C_S
pubs.acs.org/doi/10.1021/ja…

Please join us in congratulating Sumon, Nitish, & Tong for achieving photoinduced, site-selective β- and γ-borylation of amines using a new, easily installable/ removable radical translocating group, enabling late-stage derivatization. Out now in @J_A_C_S
pubs.acs.org/doi/10.1021/ja…

Aryl radical-mediated dual HAT enables direct CDC of aldehydes & alkenes to form skipped enones with high chemoselectivity! Congrats, Sidhant & Pramod, for developing Ni-Catalyzed Cross-Dehydrogenative Coupling toward Skipped Enones, now out in @J_A_C_S
pubs.acs.org/doi/full/10.10…

Our latest discovery on Ni-catalyzed directed halogen atom transfer(DIXAT) is out in @J_A_C_S! A directing group enables Ni to selectively generate Ar• from ArBr in presence of much weaker Ar–I bonds. A 1,n-HAT follows, enabling remote arylation of amines shorturl.at/inNPK