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Quinton Bruch

@QJBruch

Assistant Prof. @StonyBrookChem. Former member of the Radosevich and @DocAJMM Labs. Building organometallic solutions for a better world.
Stony Brook, NY thebruchlab.com Joined August 2017
244 Following 402 Followers 60 Posts

Latest posts 5

Quinton Bruch @QJBruch
Check out our (Noah, Josh, and @DocAJMM) recent study in @InorgChem on the oxidative addition of a P-O bond! This project all started with an attempted synthetic shortcut to access a NiH, but instead led to the discovery of new reactivity at low-valent Ni!
pubs.acs.org/doi/10.1021/ac…
pubs.acs.org Oxidative Addition of a Phosphinite P–O Bond at Nickel Abstract. Oxidative addition is an essential elementary reaction in organometallic chemistry and catalysis. While a diverse array of oxidative addition rea
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Quinton Bruch @QJBruch
Excited for this paper from my postdoc w/ @sunflower423 to be in print @J_A_C_S ! We showed that it is possible to invert traditional metal-ligand relationships and drive catalytic reactions solely from a hydridic P site without invoking reactivity at Ru!
doi.org/10.1021/jacs.2…
pubs.acs.org Metal–Ligand Role Reversal: Hydride-Transfer Catalysis by a Functional Phosphorus Ligand with a... Abstract. Hydride transfer catalysis is shown to be enabled by the nonspectator reactivity of a transition metal-bound low-symmetry tricoordinate phosphoru