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Esmu mājās
Rūdolfs Beļaunieks
@Rudolfs_B
Citi saka, ka esmu garš
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Finally, alongside Rasma and Artjoms, our paper from Turks' lab at @RTU_LV has been published in JOC @JOC_OL. It discusses the synthesis of various 5-membered heterocycles from propargyl silanes via 1,2-silyl migration! Check it out: pubs.acs.org/doi/abs/10.102…
pubs.acs.org 1,2-Silyl Shift-Induced Heterocyclization of Propargyl Silanes: Synthesis of Five-Membered Hetero... Abstract. Propargyl silanes with a terminal alkyne moiety undergo a 1,2-silyl shift when activated with electrophiles such as H+, Br+, I+, and PhSe+. A met Making good use of the β-silicon effect! From Turks' lab together with Mikus @pacans94, our effort for 1,3-difunctionalization of propargyl silanes via a concomitant 1,2-silyl shift is finally out in OrgLett. @JOC_OL @RTU_LV pubs.acs.org/doi/full/10.10…
pubs.acs.org 1,3-Difunctionalization of Propargyl Silanes with Concomitant 1,2-Silyl Shift: Synthesis of Allyl... Abstract. Terminal alkynes with a silyl group at the propargylic position upon activation with electrophiles such as N-bromosuccinimide undergo (E)-selecti It was quite the adventure! Thank you, @BeilsteinInst, for organising such a wonderful event! Full of good talks and new ideas! #BeilsteinAlkene
