@SchulzGroup
chemistry-europe.onlinelibrary.wiley.com New Insights into Poly(Dichlorophosphazene) Synthesis via Me3Si─N═PCl3 Polymerization: An Experim... Poly(dichlorophosphazene) synthesis via Me3Si─N═PCl3 polymerization was reinvestigated using quantum chemical calculations and experiments. A cationic initiator (Ph3PCl2) enables ambient-temperature... Our latest @ChemicalScience paper reports the first crystal structure of hydrazoic acid bound to a transition metal. Cryogenic photolysis reveals the elusive triplet dirhodium imidogen intermediate enabling stereospecific NH aziridination of olefins. doi.org/10.1039/D6SC02…View quoted post on X
2.5 years since we first discovered this compound and it’s finally out in @NatureChemistry! Have a read to learn about some surprisingly stable {N4} radical anions and there not so stable (and explosive) dianionic counterparts! nature.com/articles/s4155…View quoted post on X
