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Fast ionic motion in a Na thiophosphate can drive structural change: using high-temperature Na-23 and P-31 #NMR up to 650 °C (@PANACEA_NMR), we show that Na-ion diffusion in Na4P2S6 precedes and initiates the transition to its rotor phase. JACS: doi.org/10.1021/jacs.5…
The bulk Na+ #ionic #conductivity of W-doped Na3SbS4 can reach an impressive 96 mS/cm at room temperature as extrapolated from low-T impedance spectroscopy down to – 160 °C; excellent agreement with diffusion coefficients from AIMD and QENS. JACS: doi.org/10.1021/jacs.5…
... lithiation of LATP solid #electrolytes studied by Li-(7) #NMR - see our latest study in Communications Chemistry. nature.com/articles/s4200…
