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chemistry-europe.onlinelibrary.wiley.com Terminal Selective Arylation of Inert Alkanes via Radical‐Organometallic Crossover Selectivity is an essential part of organic synthesis and key to synthetic efficiency. However, selectivity is challenging to achieve in hydrocarbon molecules. Herein we report a mild and direct... 
www.nature.com Photocatalytic anti-Markovnikov hydro- and haloazidation of alkenes Nature Communications - Hydroazidation of alkenes provides a direct entry to alkyl azides which are prevalent structural motifs in medicine development and chemical biology probes. Here the authors... 
onlinelibrary.wiley.com Overcoming Challenges in Small‐Ring Transfer: Direct Decarboxylative Hydroalkylation of Alkenes via... Herein, we present a catalytic approach for the direct decarboxylation of challenging CF3-cyclopropyl and cyclobutyl carboxylic acids using cooperative iron-thiol catalysis. This strategy enables... 
pubs.acs.org Mild Hydroalkylation of Terminal Olefins Via Decatungstate/Thiol Cooperative Photocatalysis Abstract. Here we report the use of a tetrabutylammonium decatungstate (TBADT)/thiol photocatalytic system for selective addition of acetone and other simp 